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991.
Qingwen Qin Zhiyang Cheng Hui Jia Zhao Cui Guang Yang Min Sun Jie Wang 《American Institute of Chemical Engineers》2022,68(4):e17580
To shed light on the effect of pulse flow on shear force and membrane fouling, the pulse frequency and flow velocity based on fiber Bragg grating (FBG) sensing technology were studied. The results show that there is a threshold for this synergy between the pulse frequency and flow velocity, which forms more easily at a high pulse frequency and low flow velocity. Moreover, the transition from pulse flow to continuous flow affects the shear force distribution with the membrane module height. Besides, at the same volumetric flow, Re gradually reaches a plateau as the pulse frequency increases from 1 to 5 Hz, and the membrane fouling control has a better flux recovery, which can reach a maximum of 28.89%. Finally, the results also show that the combined effect of high pulse frequency and low flow velocity would be higher than that of low pulse frequency and high flow velocity. 相似文献
993.
994.
995.
Chaoqun Xia Shi Liu Baining Cui Mingjun Li Hongshui Wang Chunyong Liang Phong A. Tran Yan Wang Huan Zhou Lei Yang 《International Journal of Applied Ceramic Technology》2022,19(5):2437-2449
Development of reliable ultraviolet (UV) blockers is crucial for UV radiation protection applications such as sunscreen and UV-resistant fabric. To date, zinc oxide (ZnO) has been extensively used as a physical UV blocker worldwide but has also been criticized for with its unfavored UV-induced reactive oxygen species (ROS) generation phenomena. As an attempt to suppress the photocatalytic activity of ZnO without compromising its UV absorbance property, amorphous selenium (Se) nanoparticles (NPs) were incorporated to ZnO using a facile and cost-effective coprecipitation method. Additionally, this process also enables an economical synthesis route for harvesting amorphous Se NPs from an aqueous medium. The ZnO–Se composites were thoroughly characterized to confirm its enhanced UV absorptivity combined with high transparency in the visible light range and to understand the interaction between ZnO and Se. Besides, Se-induced photocatalytic activity suppression of ZnO was demonstrated using methylene orange as an indicator. In vitro study revealed that ZnO–Se composite had improved biocompatibility over ZnO but comparable bacteriostasis ability under full-spectrum light irradiation. These results suggest that ZnO–Se composite is a promising UV blocker with advantages of facile synthesis, UV-induced ROS generation diminishment and biocompatibility. 相似文献
996.
Hongqiang Cui Yongze Cao Ying Li Lei Li Yuhang Zhang Guojian Li Yichao Wang Xiangping Li Baojiu Chen 《International Journal of Applied Ceramic Technology》2022,19(6):3358-3366
A series of Sr2.99-x(PO4)2:.01Er3+/xYb3+ (x = .02, .04, .06, .08, .10) phosphors in the presence of impurity Tm3+ were synthesized by high temperature solid-state method, and X-ray diffraction results show that these samples are pure R-3 m(166) space group phase. The upconversion luminescence (UCL) of Er3+ and impurity Tm3+ under 980-nm laser excitation were investigated, and the results show that the intense blue UCL of impurity Tm3+ and thermal enhancement of 2H11/2→4I15/2 of Er3+ simultaneously exist. When Er3+ doping concentration is kept at .01, both the blue UCL intensity of impurity Tm3+ and green and red UCL intensity of Er3+ reach the maximum at Yb3+ doping concentration of .08. The thermal enhancement effect of 2H11/2→4I15/2 of Er3+ was observed as high as 3.27 times from 303 to 723 K, which is because of lattice distortion and phonon-assisted transition. In addition, the optical temperature performance of Sr2.91(PO4)2:.01Er3+/.08Yb3+ sample was studied, and the maximum absolute temperature sensitivity was calculated as .00623 K−1 at 538 K. This study suggests that Sr3(PO4)2:Er3+/Yb3+ phosphors in the presence of impurity Tm3+ have a promising application prospect as optical temperature sensor at high temperature. 相似文献
997.
998.
Enzyme–metal hybrid catalysts bridge the gap between enzymatic and heterogeneous catalysis, which is significant for expanding biocatalysis to a broader scope. Previous studies have demonstrated that the enzyme–metal hybrid catalysts exhibited considerably higher catalytic efficiency in cascade reactions, compared with that of the combination of separated enzyme and metal catalysts. However, the precise mechanism of this phenomenon remains unclear. Here, we investigated the diffusion process in enzyme–metal hybrid catalysts using Pd/lipase-Pluronic conjugates and the combination of immobilized lipase (Novozyme 435) and Pd/C as models. With reference to experimental data in previous studies, the Weisz–Prater parameter and efficiency factor of internal diffusion were calculated to evaluate the internal diffusion limitations in these catalysts. Thereafter, a kinetic model was developed and fitted to describe the proximity effect in hybrid catalysts. Results indicated that the enhanced catalytic efficiency of hybrid catalysts may arise from the decreased internal diffusion limitation, size effect of Pd clusters and proximity of the enzyme and metal active sites, which provides a theoretical foundation for the rational design of enzyme–metal hybrid catalysts. 相似文献
999.
1000.
针对不利环境作用、损伤等易造成结构局部损伤且刚度退化程度不均匀的问题,以受弯梁为研究对象,从构件动力特性入手,综合考虑损伤前后的模态挠度曲率和固有频率变化,提出了基于频率变化率的刚度非均匀退化识别方法。首先,在柔度矩阵的基础上推导模态挠度曲率,通过损伤前后模态挠度曲率的改变量识别损伤位置参数,判定损伤区域;其次,对损伤区域进行节段划分,从欧拉-伯努利梁的动力方程出发建立损伤程度、损伤区域位置参数与固有频率之间的矩阵函数,实现直接利用频率值变化评估构件不同区域损伤程度。研究结果表明,该方法能很好地识别结构局部损伤位置和损伤程度,尤其是对于结构局部刚度不均匀退化的评估具有明显的优势。 相似文献